Which of the following complexes is diamagnetic and tetrahedral?

  • A
    $[Ni(CO)_4]$
  • B
    $[HgI_4]^{2-}$
  • C
    $[Fe(CO)_4]^{2-}$
  • D
    All of these

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$[Ni(CO)_4]$ is diamagnetic. Which of the following statements is correct for this complex?

Match the following:
Column-$1$ (Reaction)Column-$2$ (Main product)
$A$. $4FeCl_3 + 3K_4[Fe(CN)_6] \rightarrow$$I$. $Fe_4[Fe(CN)_6]_3$
$B$. $ZnCl_2 + 4NaOH \rightarrow$$V$. $Na_2ZnO_2$
$C$. $2FeCl_3 + H_2S \rightarrow$$II$. $FeCl_2$

When a metal rod $M$ is dipped into an aqueous colourless concentrated solution of compound $N$,the solution turns light blue. Addition of aqueous $NaCl$ to the blue solution gives a white precipitate $O$. Addition of aqueous $NH_3$ dissolves $O$ and gives an intense blue solution.
$1.$ The metal rod $M$ is
$(A)$ $Fe$ $(B)$ $Cu$ $(C)$ $Ni$ $(D)$ $Co$
$2.$ The compound $N$ is
$(A)$ $AgNO_3$ $(B)$ $Zn(NO_3)_2$
$(C)$ $Al(NO_3)_3$ $(D)$ $Pb(NO_3)_2$
$3.$ The final solution contains
$(A)$ $[Pb(NH_3)_4]^{2+}$ and $[CoCl_4]^{2-}$
$(B)$ $[Al(NH_3)_4]^{3+}$ and $[Cu(NH_3)_4]^{2+}$
$(C)$ $[Ag(NH_3)_2]^{+}$ and $[Cu(NH_3)_4]^{2+}$
$(D)$ $[Ag(NH_3)_2]^{+}$ and $[Ni(NH_3)_6]^{2+}$
Give the answer for questions $1$,$2$ and $3$.

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